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MCB-143 Lecture 2023-04-13 at 08:57
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Imines, Enamines and Reductive Amination, Wolff-Kishner Reduction, Wittig Reaction, Baeyer-Villiger Oxidation, Enolate Ion Formation and Tautomerization, Halogenation Alpha to a Carbonyl in Acid and…
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IUPAC Nomenclature of Ketones, General Carbonyl Properties; Spectroscopy of Aldehydes/Ketones (H NMR, C NMR, IR), Review of Carbonyl Formations, General Nucleophilic Acyl Addition in Base and Acid,…
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Determining Aromatic vs. Anti-Aromatic vs. Non-Aromatic, Aromatic Ions, Aromatic Heterocycles, General Electrophilic Aromatic Substitution Mechanism, Halogenation of Benzene, Nitration of Benzene,…
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Electrocyclic Reactions - Examples, Introduction to Aromaticity, Common and IUPAC Nomenclature of Benzenes, Spectroscopy of Benzenes (IR, H NMR, C NMR), Determining Aromaticity / Huckel's Rules,…
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Electrophilic Addition to Conjugated Dienes (Thermodynamic vs. Kinetic Control), Extrapolation to Extended Pi Systems, Diels-Alder Reaction/Mechanism, Stereochemistry of Diels-Alder Reactions,…
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Lecture Starts at 56:20 Reactions Allylic Systems - Allylic Radical Halogenation, Delocalization and Conjugated Dienes, Molecular Orbitals of Conjugated Dienes, Consequences of Conjugation on…
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Electrophilic Addition to Alkynes - Hydrohalogenation, Halogenation, Hydration; Reactions of Vinyl Halides, Heck Reaction, Introduction to Delocalization and Allylic Systems, Molecular Orbitals of…
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Nomenclature of Alkynes, Properties of Alkynes (Pi Bonds, Stability, pKa), Spectroscopy of Alkynes (IR, H NMR, C NMR), Formation of Alkynes via Dehydrohalogenation (E2), Alkynyl Anions as…
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Alkenes with Carbenes - Forming Cyclopropane and Epoxides, Review of Epoxide Ring Opening, Syn-Diol Formation with OsO4, Ozonolysis, Radical (Anti-Markovnikov) Addition to Alkenes
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Relative Stability of Substituted Alkenes, Formation of Alkenes via Elimination of Haloalkanes (E2) and Alcohols (E1), Hydrogenation of Alkenes, Basic Principles of Electrophilic Addition;…
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Structure and Properties of Alkenes, Strength of Pi Bonds, Spectroscopy of Alkenes (IR, H NMR, C NMR, Geminal, Vicinal, and Allylic Coupling), Mass Spectrometry
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Syllabus, Alkene Nomenclature, Assigning E/Z, Alkenyl Groups
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Videos and all other materials are copyright 2021 Matthias Köppe and shared as Open Educational Resources subject to the Creative Commons Attribution-ShareAlike 3.0 Unported (CC BY-SA 3.0)…
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